非均相负载型Fenton催化剂材料设计合成研究进展

程静 王春颖 郑荣伟 吴晓峰 王翠翠

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中国农村水利水电 ›› 2019 ›› (11) : 125-128.
水环境与水生态

非均相负载型Fenton催化剂材料设计合成研究进展

  • 程 静1,2 ,王春颖3 ,郑荣伟1 ,吴晓峰4 ,王翠翠5 
作者信息 +

New Research Progress in Development of Heterogeneous Fenton Supported Catalyst

  • CHENG Jing1,2 ,WANG Chun-ying3 ,ZHENG Rong-wei 1 ,WU Xiao-feng4 ,WANG Cui-cui 5
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稿件信息 +

摘要

由于我们国家在经济和社会建设上的大力发展和人口的不断增加,污水排放量也屡创新高。而对排放污水的不当处理会造成不同程度的环境污染。作为高级氧化技术的一种,绿色芬顿(Fenton)催化氧化法能产生具有强氧化能力的羟基自由基(?OH)等活性基团,氧化体系中的有机污染物。与传统方法相比,其具有条件温和、氧化速率快、对氧化对象无选择性等优点。另外由于非均相Fenton催化技术的发展解决了目前均相Fenton反应存在的问题,因而成为水处理领域的研究热点。本文综述了近几年有关非均相Fenton催化剂载体的研究,旨在寻找使Fenton催化剂能发挥更好的催化效果的载体。

Abstract

Due to the vigorous development of country in economic and social construction and the increasing population,sewage discharges have also hit record highs. Improper disposal of discharged sewage will cause different levels of environmental pollution. As a kind of advanced oxidation technology,the green Fenton catalytic oxidation method can generate active groups such as hydroxyl radicals ( ·OH) with strong oxidizing ability and organic pollutants in the oxidation system. Compared with the traditional method,it has the advantages of mild conditions,fast oxidation rate and no selectivity to oxidized objects. In addition,due to the development of heterogeneous Fenton catalytic technology,the problem of the current homogeneous Fenton reaction is solved,which has become a research hotspot in the field of water treatment. In this paper,the research on heterogeneous Fenton catalyst carrier in recent years is reviewed,aiming at finding a carrier that can make Fenton catalyst play a better catalytic effect. 

关键词

Fenton / 非均相负载型催化剂 / 载体 / 废水处理 / 结构特性 

Key words

Fenton / heterogeneous supported catalyst / support / wastewater treatment / structure and property

基金

浙江省水利厅科技项目 ( RC1725) ; 浙江省教育厅项目 ( Y201840641) ; 浙江省新苗人才计划项目( 2018R445001) 。

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导出引用
程静 王春颖 郑荣伟 吴晓峰 王翠翠. 非均相负载型Fenton催化剂材料设计合成研究进展[J].中国农村水利水电, 2019(11): 125-128
CHENG Jing, WANG Chun-ying, ZHENG Rong-wei, WU Xiao-feng, WANG Cui-cui. New Research Progress in Development of Heterogeneous Fenton Supported Catalyst[J].China Rural Water and Hydropower, 2019(11): 125-128

参考文献

[1] 王犇, 朱现波, 赵倩, 刘朔. 负载型Fenton催化剂处理有机废水的研究进展 [J]. 工业水处理, 2016, 36: 6-11.
[2] A. Babuponnusami, K. Muthukumar. A review on Fenton and improvements to the Fenton process for wastewater treatment [J]. J. Environ. Chem. Eng. 2014, 2: 557-572.
[3] E. Brillas, I. Sirés, M.A. Oturan. Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry [J]. Chem. Rev. 2009, 109: 6570-6631.
[4] S. Wang. A comparative study of Fenton and Fenton-like reaction kinetics in decolourisation of wastewater [J]. Dyes and Pigments2008, 76: 714-720.
[5] J.J, Pignatello, E. Oliveros, A. MacKay. Advanced Oxidation Processes for Organic Contaminant Destruction Based on the Fenton Reaction and Related Chemistry [J]. Crit.?Rev.?Env.?Sci.?Technol. 2006, 36:1-84.
[6] N. Mahata, A.R. Silva, M.F.R. Pereira, C. Freire, B. de Castro, J.L. Figueiredo. Anchoring of a [Mn (salen) Cl] complex onto mesoporous carbon xerogels [J]. J.?Colloid?Interface?Sci.?2007, 311: 152-158.
[7] K. Kadirvelu, J. Goel, C. Rajagopal. Sorption of lead, mercury and cadmium ions in multi-component system using carbon aerogel as adsorbent [J]. J. Hazard. Mater. 2008, 153: 502-507.
[8] B.S. Girgis, A.A. Attia, N.A. Fathy. Potential of nano-carbon xerogels in the remediation of dye-contaminated water discharges [J]. Desalination2011, 265: 169-176.
[9] C. Moreno-Castilla, F.J. Maldonado-Hódar. Carbon aerogels for catalysis applications: An overview [J]. Carbon2017, 43: 455-465.
[10] N. Job, B. Heinrichs, S. Lambert, J.P. Pirard, J.F. Colomer, B. Vertruyen, J. Marien. Carbon xerogels as catalyst supports: Study of mass transfer [J]. AIChE J. 2006, 52: 2663-2676.
[11] L. Zubizarreta, A. Arenillas, J.P. Pirard, J.J. Pis, N. Job. Tailoring the textural properties of activated carbon xerogels by chemical activation with KOH [J]. Microporous and Mesoporous Mater. 2008, 115: 480-490.
[12] M.S. Contreras, C.A. Páez, L. Zubizarreta, A. Léonard, S. Blacher, C.G. Olivera-Fuentes, N. Job. A comparison of physical activation of carbon xerogels with carbon dioxide with chemical activation using hydroxides [J]. Carbon2010, 48: 3157-3168.
[13] R.S. Ribeiro, N.A. Fathy, A.A. Attia, M.T. Adrián, Silva, J.L.Faria, H.T. Gomes. Activated carbon xerogels for the removal of the anionic azo dyes orange ii and chromotrope 2r by adsorption and catalytic wet peroxide oxidation [J]. J. Chem. Eng. 2012, 195: 112-121.
[14] S.A. Messele, O.S.G.P. Soares, J.J.M. órf?o, C. Bengoa, J. Font. Zero-valent iron supported on nitrogen-doped carbon xerogel as catalysts for the oxidation of phenol by fenton-like system [J]. Environ.?Technol. 2018, 39: 2951-2958.
[15] A. Tiya-Djowe, S. Laminsi, G.L. Noupeyi, E.M. Gaigneaux. Non-thermal plasma synthesis of sea-urchin like α-FeOOH for the catalytic oxidation of Orange II in aqueous solution [J]. Appl. Catal. B Environ. 2015, 176: 99-106.
[16] G. Huang, C. Zhang, Y. Long, J. Wynn, Y. Liu, W. Wang, J. Gao. Low temperature preparation of α-FeOOH/reduced graphene oxide and its catalytic activity for the photodegradation of an organic dye [J]. Nanotechnology2013, 24: 395601.
[17] M. Tekbas, H.C. Yatmaz, N. Bektas. Heterogeneous Photo-Fenton Oxidation of reactive Azo Dye Solutions Using Iron Exchanged Zeolite as Catalyst [J].Micropor Mesopor Mater. 2008, 115(3): 594-602.
[18] 孙盼华, 周培国, 张齐生, 张楠. 载铁竹炭非均相 Fenton催化剂处理苯酚废水的研究 [J]. 工业水处理, 2015, 35 : 71-74.
[19] 陈娴, 高永, 徐旭. FeY 催化剂光助 Fenton 法降解亚甲基蓝染料废水 [J].环境科学与技术, 2012, 35: 139-142.
[20] 张启伟, 王桂仙. 竹炭对饮用水中氟离子的吸附条件研究 [J].广东微量元素科学, 2005, 12: 63-66.
[21] L. Qin, Z. Li, Z. Xu, X. Guo, G. Zhang. Organic-acid-directed assembly of iron–carbon oxides nanoparticles on coordinatively unsaturated metal sites of MIL-101 for green photochemical oxidation [J]. Appl. Catal. B Environ. 2015, 179: 500-508.
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